Bernard,

We've successfully used ASAPRatio for heavy dimethyl labeled
quantitation using the following workflow, which might help you get to
where you want:

* Run *two* searches, with the light and heavy methyl n-term and
lysine mods specified as *static* modifications, i.e.

Search 1: Dimethyl (K) + Dimethyl (n-term) as static mods.
Search 2: Dimethyl:2H4 (K) + Dimethyl:2H4 (n-term) as static mods.

* Run xinteract on the resulting pair of search results using the
static mods option for ASAPRatio, i.e.

-A-lnK-S-r0.05

There's no need to run XPRESS if you are only interested in ASAPRatio
results.

DT


On 11 Mar, 07:05, Bernt <[email protected]> wrote:
> Dear all,
>
> I have a question pertaining to ASAPRatio.
>
> Can I actually get ASAPRatio to give me a ratio of Kmethylated / Kheavy
> +methylated (i.e. K142/K148)? If it can be done, how do I specify on
> the commandline different modified forms of Lys as the numerator and
> denominator of the ratio? Both modifications have been specified under
> variable mods in Xtandem. Does Xpress need to be specified everytime
> ASAPRatio is run, or can it be omitted? Can the following work?
>
> xinteract  -NinteractHeavyMethyl2.pep.xml -p0 -l6 -OA -A-
> lR170.11676K142.11061-F-r0.1-mK148.13061R180.12476
> "*HeavyMethyl.tandem.pep.xml"
>
> I also tried specifying static mod on Lys (i.e. 1...@k), and variable
> mod of 2...@k to represent the Heavy+Methyl form in Xtandem first,
> then :
>
> xinteract  -Ninteractstatic.pep.xml -p0 -l6 -OA -X-nR,10K,6 -A-lRK-F-
> r0.1-mK148.13061R180.12476 "*static.tandem.pep.xml"
>
> But in this case, PeptideProphet's probabilities were all 0,
> presumably because there were very few significant peptide assignments
> due to the static mod specified on all Lys. Does anybody have any idea
> how I can get around this problem with ASAPRatio?
>
> I look forward to any suggestions. Thanks in advance.
>
> Cheers,
> Bernard

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