This question comes up semi-regularly; here's the explanation obtained from
the author of X!Tandem many years ago:

http://tools.proteomecenter.org/wiki/index.php?title=TPP:X!Tandem_and_the_TPP#X.21Tandem_default_modifications


On Sat, Feb 15, 2014 at 12:04 AM, Konstantinos Vougas <[email protected]>wrote:

> Hello,
>
> I have set the following modifications for an X!Tandem search in TPP:
>
>   <note type="input" label="residue, modification mass">57.021464@C</note>
>   <note type="input" label="residue, potential modification
> mass">15.994915@M</note>
> <note type="input" label="residue, potential modification mass">15.994915@P
> </note>
> <note type="input" label="residue, potential modification motif"></note>
> <note> You can specify a variable modification only when present in a
> motif. For instance, 0.998@N!{P}[ST] is a deamidation modification on N
> only if it is present in an N[any but P][S or T] motif (N-glycosite).
> </note>
> <note type="input" label="protein, N-terminal residue modification
> mass"></note>
>   <note type="input" label="protein, C-terminal residue modification
> mass"></note>
> <note> These are *static* modifications on the PROTEINS' N or C-termini.
> </note>
>
> ... hence Carbamidomethylation of C as Fixed Modification and M & P
> Oxidation as varible modifications and no N or C terminal modificaations.
>
> In my results I get peptides like this:
>
> R.*Q[111.03]*TVSWAVTPK.S
> M.*n[43.02]*HGGGP[113.05]P[113.05]SGDSAC[160.03]P[113.05]LR.T
>
>
> What are these Q[111.03] & n[43.02]. Actually I know that n[43.02] is
> acetylated peptide alpha-amine but how come it is there?
>
> Thanks in advance
>
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