Hi Oded,

It is likely there is an issue with PTMProphet that doesn't recognize
the modifications in your dataset.  If you can share a portion of your
data for testing purposes I can help troubleshoot further.

Thank you!
-David

On Tue, Jul 1, 2014 at 5:33 AM, Oded <[email protected]> wrote:
> Hi all,
> I am using TPP 4.7.1 on Win7 and currently trying to analyze data of
> dimethylated phosphopeptides searched with X!tandem.
> The searches were done by using 2 sets of fixed modifications for the Cys
> alkylation plus light or heavy dimethylation on N-term and K  with STY
> phosphorylation, Met-Ox and protein N-term acetylation as set as variable
> modifications.
> When I try to run PTM prophet (following peptide prophet and iprophet runs)
> I getting the following error:
>
>
> EXECUTING: run_in c:/Inetpub/wwwroot/ISB/data/Oded/Enzo/Phospho_June2014;
> c:\Inetpub\tpp-bin\PTMProphetParser
> STY,79.966,C,57.021464,n,34.063117,K,34.063117,M,15.99 MZTOL=0.1
> c:/Inetpub/wwwroot/ISB/data/Oded/Enzo/Phospho_June2014/interactNative1.ipro.pep.xml
> interactNative
> INFO: Writing file interactNative1.ptm.pep.xml ...
> INFO: Reading file
> c:/Inetpub/wwwroot/ISB/data/Oded/Enzo/Phospho_June2014/interactNative1.ipro.pep.xml
> ...
> WARNING: Cannot initialize for sequence: n[71]M[147]KDEPRSTNLFMK, unknown
> mods may exist in spectrum CHH20140618_M1HTiO2_100mM.03738.03738.2
> WARNING: Cannot initialize for sequence: n[35]K[162]S[167]PAAAR, unknown
> mods may exist in spectrum CHH20140618_M1HTiO2_100mM.03900.03900.2
> WARNING: Cannot initialize for sequence: n[35]VPS[167]RHINIGR, unknown mods
> may exist in spectrum CHH20140618_M1HTiO2_100mM.04358.04358.2
> WARNING: Cannot initialize for sequence:
> n[35]EGEEPT[181]VYSDEEEPK[162]DESAR, unknown mods may exist in spectrum
> CHH20140618_M1HTiO2_100mM.04499.04499.3
> WARNING: Cannot initialize for sequence: n[35]GTPGPAVR, unknown mods may
> exist in spectrum CHH20140618_M1HTiO2_100mM.05584.05584.2
>     WARNING: Unrecognized mod on peptide: n[35]SCFESS[167]PDPELK[162]
>     WARNING: Unrecognized mod on peptide: n[35]SCFESS[167]PDPELK[162]
>     WARNING: Unrecognized mod on peptide: n[35]SCFESS[167]PDPELK[162]
>     WARNING: Unrecognized mod on peptide: n[35]SCFESS[167]PDPELK[162]
>     WARNING: Unrecognized mod on peptide: n[35]SCFESS[167]PDPELK[162]
>     WARNING: Unrecognized mod on peptide: n[35]SCFESS[167]PDPELK[162]
>     {this appear 100-200 times}
>
>
>
> This application has requested the Runtime to terminate it in an unusual
> way.
> Please contact the application's support team for more information.
>
> command "c:\Inetpub\tpp-bin\PTMProphetParser
> STY,79.966,C,57.021464,n,34.063117,K,34.063117,M,15.99 MZTOL=0.1
> c:/Inetpub/wwwroot/ISB/data/Oded/Enzo/Phospho_June2014/interactNative1.ipro.pep.xml
> interactNative1.ptm.pep.xml" failed: No such process
>
>
> I tried adding both heavy and light dimethylation (+28 and +34 on K and
> N-term) just light and just heavy (as shown above), the the mass of the
> DiMet N-term as it appear in the pepXML (+35 or +29)  but the error is still
> the same...
> Is there a way to sort this?
> Many thanks,
> Oded
>
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