Thats interesting. I went back to check my Xtandem parameters & this
parameter is set to 'no' so it seems there is some other native logic
within Xtandem that controls this behavior.

<note type="input" label="protein, quick acetyl">no</note>

Regards
Vidya

On Fri, Jun 7, 2019 at 2:19 PM Jimmy Eng <[email protected]> wrote:

> I believe this X!Tandem parameter affects the initiator methionine
> cleavage:  https://www.thegpm.org/TANDEM/api/pqa.html
> And I'm not aware of any RefreshParser parameters that control this
> behavior; I am using an older version (5.0.0) of the TPP though.
>
> On Fri, Jun 7, 2019 at 2:10 PM Vidya Venkatraman <[email protected]>
> wrote:
>
>> Thanks Jimmy for your prompt response.
>>
>> I do see that for isoform P06396-2, the preceding methionine is the first
>> residue of the sequence and I used both comet & tandem for the database
>> search.
>>
>> For Comet search, I did have the "clip_nterm_methionine
>> <http://comet-ms.sourceforge.net/parameters/parameters_201801/clip_nterm_methionine.php>"
>> parameter set to "1" so you explanation makes sense.
>>
>> But for Tandem search, I am not sure if Tandem has an equivalent
>> parameter. But i can see that the tandem peptideprophet pepxml also
>> identifies this peptide as unique to isoform P06396-2.
>>
>> <spectrum_query
>> spectrum="XL_150506_IDA_PDAY_F7_proteinpilot.09460.09460.2"
>> start_scan="9460" end_scan="9460" precursor_neutral_mass="1096.5930"
>> assumed_charge="2" index="28557" retention_time_sec="2248.41">
>> <search_result>
>> <search_hit hit_rank="1" peptide="VVEHPEFLK" peptide_prev_aa="M"
>> peptide_next_aa="A" protein="sp|P06396-2|GELS_HUMAN"
>> protein_descr="Isoform 2 of Gelsolin OS=Homo sapiens OX=9606 GN=GSN"
>> num_tot_proteins="1" num_matched_ions="17" tot_num_ions="16"
>> calc_neutral_pep_mass="1096.5917" massdiff="0.001" num_tol_term="2"
>> num_missed_cleavages="0" is_rejected="0">
>>
>> Do you know if there is a parameter similar to 'clip_nterm_methionine' in
>> tandem as well? and
>> Does RefreshParser have any parameters to control this behavior?
>>
>> Many Thanks
>> Vidya
>>
>>
>>
>>
>>
>>
>>
>>
>> On Wed, Jun 5, 2019 at 11:27 AM Jimmy Eng <[email protected]> wrote:
>>
>>> Without more info, here's my educated guess at an explanation:  that
>>> peptide is not a fully tryptic peptide in the proteins you list as it is
>>> preceded by a methionine residue.  For isoform P06396-2, the preceding
>>> methionine is the first residue of the sequence and I'm assuming you did a
>>> Comet search with the "clip_nterm_methionine
>>> <http://comet-ms.sourceforge.net/parameters/parameters_201801/clip_nterm_methionine.php>"
>>> parameter set to "1".  With that start methionine removed, this allowed
>>> that peptide to be fully tryptic in that particular isoform hence only that
>>> isoform is listed as a matched protein.  The enzyme context does matter
>>> with RefreshParser; it's simply not a peptide string match.
>>>
>>> On Wed, Jun 5, 2019 at 11:15 AM Vidya Venkatraman <
>>> [email protected]> wrote:
>>>
>>>> Hi Everyone,
>>>>
>>>> I am trying to run xinteract with the -D option so that RefreshParser
>>>> can use the fasta database to find all proteins corresponding to
>>>> identified peptides.
>>>>
>>>> This is the command I am using:
>>>> xinteract -OARPwd -dDECOY_ -PPM -nR
>>>> -D/scratch/venkatramanv/iphronesis/reference_files/Databases/UP_Human_Rev_Can+Iso_20190410_DECOY.fasta
>>>> -N/scratch/venkatramanv/iphronesis/platform_workspace/jobs/SJOB2122/peptideprophet/2122_PDAY_DDA_Isoforms.comet.interact.pep.xml
>>>> *.comet.pep.xml
>>>>
>>>> Despite using the -D database option, i noticed that some peptides in
>>>> the interact.pep.xml are matched uniquely to a specific isoform (even
>>>> though that peptide is not proteotypic or unique to any isoform).
>>>>
>>>> For example:
>>>>
>>>> <spectrum_query
>>>> spectrum="XL_150506_IDA_PDAY_F8_proteinpilot.08799.08799.2"
>>>> start_scan="8799" end_scan="8799" precursor_neutral_mass="1096.592165"
>>>> assumed_charge="2" index="20868" retention_time_sec="2254.3">
>>>> <search_result>
>>>> <search_hit hit_rank="1" peptide="VVEHPEFLK" peptide_prev_aa="M"
>>>> peptide_next_aa="A" protein="sp|P06396-2|GELS_HUMAN" num_tot_proteins="
>>>> 1" num_matched_ions="11" tot_num_ions="16"
>>>> calc_neutral_pep_mass="1096.591696" massdiff="0.000470" num_tol_term="1"
>>>> num_missed_cleavages="0" num_matched_peptides="6184">
>>>> <search_score name="xcorr" value="2.205"/>
>>>> <search_score name="deltacn" value="0.575"/>
>>>> <search_score name="deltacnstar" value="0.000"/>
>>>> <search_score name="spscore" value="350.4"/>
>>>> <search_score name="sprank" value="1"/>
>>>> <search_score name="expect" value="4.94E-03"/>
>>>> <analysis_result analysis="peptideprophet">
>>>> <peptideprophet_result probability="1.0000"
>>>> all_ntt_prob="(0.0000,1.0000,1.0000)">
>>>> <search_score_summary>
>>>> <parameter name="fval" value="5.5754"/>
>>>> <parameter name="ntt" value="1"/>
>>>> <parameter name="nmc" value="0"/>
>>>> <parameter name="massd" value="0.429"/>
>>>> <parameter name="isomassd" value="0"/>
>>>> <parameter name="RT" value="1372.21"/>
>>>> <parameter name="RT_score" value="0.02"/>
>>>> </search_score_summary>
>>>> </peptideprophet_result>
>>>> </analysis_result>
>>>> </search_hit>
>>>> </search_result>
>>>> </spectrum_query>
>>>>
>>>> See attached the sequence alignment of all isoforms of GELS_HUMAN, you
>>>> can see that this peptide matches the canonical form as well as all
>>>> isoforms hence the  num_tot_proteins should be = "4" and  protein should
>>>> be ="sp|P06396|GELS_HUMAN" with <alternative_protein protein="
>>>> sp|P06396-2|GELS_HUMAN"/>,
>>>>  <alternative_protein protein="sp|P06396-3|GELS_HUMAN"/> ,
>>>> <alternative_protein protein="sp|P06396-4|GELS_HUMAN"/>
>>>>
>>>> I am happy to share all the comet.pep.xml & interact.pep.xml files
>>>> along with the fasta database via Box folder.
>>>>
>>>> Can someone please help me understand if this is expected behavior? if
>>>> so, how i can fix this?
>>>>
>>>> Regards
>>>> Vidya
>>>>
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