No it is not correct for xl peptides.  There are two peptides in every
match thus id you assume the database contains half decoys and half
targets, then there are 3/4 chance to match a decoy peptide randomly and
only 1/4 chance to match a target.  So the random xl matches will be 3/4
decoy and 1/4 target so your decoy based error rate should estimate the
number of wrong hits by taking the number of decoy matches and multiplying
by 4/3.  So wrong = decoy*4/3 and errorrate = wrong/total.

Hopefully this makes sense.

David

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