As a general rule any bushings or pieces brazed in or on a copper boiler  
should be bronze (copper/tin alloy or gun metal which is copper/tin/zinc/lead. 
The tin seems to eliminate the problem of the zinc leaving the alloy, you  
could use copper too for fittings directly on the boiler but copper is a bear 
to 
 machine cleanly (I know from when I tried to thread copper rivets for stay  
bolts). What I did was to use bronze bushings every place a line goes into our 
 out of the boiler, but ordinary brass for valve bodies, gauge glass etc as 
that  stuff can be replaced without harming the main boiler shell. The zinc 
leaving an  alloy is really apparent with some of the die casting alloys high 
in 
zinc. When  I was doing lab work in house hold appliances we had die cast 
garbage disposers  simply drop out of a sink where the zinc alloys just turned 
to 
powder. Same with  some die cast electric meter bodies used near the sea, just 
crumbled to pieces. 
 
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