Problem solved! :-)

It was our virus scanner that interfered and suppressed a SMTP command! The 
crucial tip came from 
www.frankysweb.de/exchange-2010-error-503-5-5-1-smtp-bad-sequence-of-commands-smtp-error-503/
  (in German language).

In the GData administrator, I only had to switch off checking the outgoing mail 
traffic, and everything works as before.
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