Earlier I wrote:
> The "Explanatory Supplement to the Astronomical Almanac," mentions
> alternatives to atomic time under study that may offer
> improvements. (I don't have the book handy and cannot recall what they
> are.  I will try to post a follow-up on Monday.)  I believe that
> atomic timing technology is about fifty years old now...

[...]

> Jim

On pages 60-61 of the "Explanatory Supplement to the Astronomical
Almanac," is a discussion of modern timing technologies.

2.321 Quartz-Crystal Oscillators

    ... The performance characteristics may range from 10^-4 to 10^-13
    in frequency stability per day. ...

2.322 Cesium Beam Standards

    ... laboratory cesium-beam frequency standards ... realize the
    second with the utmost accuracy (currently, 1.5 x 10^-14) and are,
    therefore, stable in the long term. ...

2.323 Hydrogen Masers

    ... The optimum stability reaches about 1 x 10^-15 for integration
    times of 1000 to 10000 seconds. ...  [S]ome hydrogen masers
    equipped with automatic tuning of the cavity and kept in
    temperature-controlled rooms have a long-term stability of the
    same order as the best cesium standards. ...

2.324 Rubidium Vapor Cells

    The rubidium clock is an appropriate device when a relatively
    low-cost clock is needed that has better stability than a quartz
    crystal clock.  The rubidium clock can reach a stability of 1 x
    10^-13 per day under the best conditions, but is subject to
    temperature- and pressure-induced frequency variations.  Ringer et
    al. (1975) describe the design and performance of a clock for the
    GPS satellites.  This clock has achieved stability of 2 x 10^-13
    per day.

2.325 Mercury Ion Frequency Standard

    The mercury-ion frequency standard uses ions that are confined in a
    small region of space by an electromagnetic field trap.  Thus the
    particles can be observed without having them collide with the
    walls, which would disturb the atomic resonance.  The mercury-ion
    isotope Hg-199 has an extremely narrow microwave resonance line at
    40507 MHz.  Although this type of frequency standard should be a
    large improvement over the cesium standard, it has an
    unfortunately low signal-to-noise ratio, resulting in limited
    short-term stability.  However, the long-term stability is very
    good, since integration can take place over a number of days
    (Winkler, 1987).

I suppose I was incorrect to call these alternatives to atomic timing.
Quartz is molecular; the maser is ultimately atomic in nature (or
perhaps molecular, I'm not sure); and the others are all atomic.  But
they are alternatives to atomic cesium clocks.

Jim
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