Hello everyone,
 
I have been testing Alecs two stage process with little sucess and have had
problems with the glyreine not falling out.I had to add lye/methanol at
three different time after the 1 stage (acid stage) in order to get the
close to 20 % glycerine to fall out. 
 
I think the problems is that I am using very different WVO, I have fats
which are solid still at + 25�C and fats that are floating at this temp,
some are sunflower and some are rapeseed and there are also some animal fats
among the ones. 
I know the problem might be a heating problem as I am not able to keep the
55�C for very long time (1 hour then the temp starts to fall). I still want
to eliminate, investigate and clearify the problem with FFA and acid
esterification of the same.
 
I made several titrations of the latest batch and found that in order to
transesterify the batch 14-16 g/lye/kg to be used (single stage process) +
20% methanol (i use as standard)
 
The questions which occured is 
 
1. How do you meassure the FFA % in the WVO can some one explain the process
I have made it according to Journey Forever instructions, is there any other
way of doing the titration? 
2. What is the FFA % in the oil if the result of the titration (Journey
forevere) is 15 g lye/kg fat and do you have to know what the VO in order be
able to find the FFA % ?
 
I made 4 small samples of WVO and added 1 ml/lit acid (Alecs formula), 2
ml/lit, 3 ml/lit and 4 ml/lit to the samples. After one night reaction I
made a new titration of sampel 1 and 3 and the result was nearly the same
for the samples 8 g/lye/kg to be used. 
 
3. Is it possible to make a titration of oil after the acid stage in the
process and are the reults reliable?
4. What happens if to much acid is added and there are no FFA to be split
and is it possible to obtain reliable results from the titration under this
kind of circumstances?
5. Is Alecs 1 ml/lit acid stage splitting all FFA or just the moste part of
the same. 
6. Can the % of acid which need to be used (splitting FFA to below 1 % in
the WVO) be determined by the titration?
7. Can some one explain the reaction and suggest a way for how to proceed
with as I see the problem with FFA.  
 
I have been making biodiesel since 1999 the single stage process is very
familiar, but now when I have commenced to obtain different WVO`s I gave me
new challanges.
 
Thank you every one for keeping up the good work for a cleaner future and
especially Keith for freely putting down the efforts ditributing information
on how to do it.
 
Best Regards from a - 8�C Finland
Tomas 
 

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