Hmm.  Could this work?  So far, all the algae energy hype has been just
that, hype.  Algae  can give you a great biofuel, but just doesn't scale
up.  It's a "small is 'beautifuel'" thing.
On Feb 25, 2014 11:22 AM, "Darryl McMahon" <dar...@econogics.com> wrote:

> http://www.maritime-executive.com/article/Continuous-
> Process-Transforms-Algae-to-Biogas-2014-02-24/
>
> Microalgae derived biogas is becoming an increasingly promising
> alternative to fossil fuels. Over the past years, researchers at the Paul
> Scherrer Institute (PSI) and EPFL have been developing SunCHem, a resource
> and energy efficient process, to cultivate microalgae and convert them into
> synthetic natural gas, a biofuel that is fully compatible with today's
> expanding gas grid. In an article published in Catalysis Today, they
> present one of the first continuous biomass to biogas conversion
> technologies.
>
> While it takes nature millions of years to transform biomass into biogas,
> it takes the SunCHem process less than an hour. The secret behind this feat
> is a process called hydrothermal gasification. First, algae-rich water is
> heated under pressure to a supercritical liquid state, to almost 400
> degrees Celsius. In this supercritical state, the water effectively
> dissolves the organic matter contained in the biomass, while inorganic
> salts become less soluble and can be recovered as a nutrient concentrate.
> By gasifying the remaining solution in the presence of a catalyst, it is
> then split into water, CO2, and the methane rich biogas.
>
> Although the approach is still about five to seven times too expensive to
> compete with natural gas, microalgae evade much of the criticism that other
> biofuel sources face. They can be grown in raceway ponds built on
> non-arable land, without competing with agricultural food production. And
> although the algae need water to grow in, they are not picky. Depending on
> the species, they can grow in freshwater or saltwater, and in the future,
> they could potentially even be used to treat wastewater. A study published
> last year estimated that, for each unit of energy spent to produce the
> biogas, between 1.8 and most optimistically 5.8 units of energy could be
> produced.
>
> To save resources, cut costs, and increase the overall efficiency of the
> process, the entire system can be run in a closed loop. "Some nutrients
> such as phosphate are limited resources, which we can recover when we
> gasify the biomass. Feeding them back into the water that we grow the algae
> in has a spectacular effect on their growth," says Mariluz Bagnoud, one of
> the two lead authors of the publication.
>
> For the publication, the researchers proved the feasibility of running the
> system as a continuous process. But they also found that feeding back water
> and nutrients over long durations leads to a degradation of the system's
> performance. "We detected the deactivation of the catalyst used in the
> gasification process and we expect the accumulation of trace amounts of
> aluminum," says Bagnoud. "The toxicity of the aluminum on the microalgae
> depends on the pH. By cultivating the algae at a neutral pH, these toxic
> effects can essentially be eliminated," she says. "Now, the next steps will
> involve fine-tuning the process to increase the longevity of the catalyst,
> which is deactivated by the sulfur contained in the microalgae," she
> concludes.
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