Do you want something like this, then:

>>> eq=a**2+b+5*c+2
>>> eq.as_coefficients_dict()
defaultdict(<type 'int'>, {1: 2, c: 5, b: 1, a**2: 1})
>>> dict(_)
{1: 2, c: 5, b: 1, a**2: 1}

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