Why this
 
d2bdy2 = b_i.diff(y_i, 2)exec("pprint({{'{0}': {0}}})".format("d2bdy2"))

 is not equivalent to
 
def assign_and_pprint(Name, Expr):
    exec("{Name} = {Expr}".format(Name=Name, Expr=Expr))
    exec("pprint({{'{Name}': {Name}}})".format(Name=Name))
assign_and_pprint("d2bdy2", b_i.diff(y_i, 2))

 Compelete example:
 
#!/usr/bin/python2.7
from sympy import *
def assign_and_pprint(Name, Expr):
    exec("{Name} = {Expr}".format(Name=Name, Expr=Expr))
    exec("pprint({{'{Name}': {Name}}})".format(Name=Name))

var("""b_i y_i nu""", positive=True)
b_i = 2**(S(2)/3) / (nu**(S(4)/3) * (y_i - 1)**(S(8)/3))
d2bdy2 = b_i.diff(y_i, 2)exec("pprint({{'{0}': {0}}})".format("d2bdy2"))
assign_and_pprint("d2bdy2", b_i.diff(y_i, 2))

 Which gives:
 
⎧                  2/3      ⎫
⎪              88⋅2         ⎪
⎨d2bdy2: ───────────────────⎬
⎪           4/3         14/3⎪
⎩        9⋅ν   ⋅(yᵢ - 1)    ⎭
⎧                          -1.33333333333333         -4.66666666666667⎫
⎨d2bdy2: 15.5212547303557⋅ν                 ⋅(yᵢ - 1)                 ⎬
⎩                                                                     ⎭

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