Why are van Gogh's paintings slowly turning white?
VanGogh_1.jpg
<http://pri-113a.kxcdn.com/sites/default/files/story/images/VanGogh_1.jpg>

Two people sit in front of Vincent Van Gogh's *Mountains at Saint Remy,
Wheat Field with White Cloud* (landscape from Saint Remy) and E*nclosed
Field with Rising Sun*. Scientists in Belgium report that red lead, a
semiconductor pigment, is the cause behind several discolorations of Van
Gogh's work.
Credit:

Luke MacGregor/Reuters

Something's different about Vincent van Gogh's work.to the Story.t's been
puzzling art curators and experts for a long time, but scientists at the
University of Antwerp discovered
<http://onlinelibrary.wiley.com/doi/10.1002/ange.201411691/abstract>the
reason why some of van Gogh's most prized works of art are turning white.

It's the plumbonacrite!

Vincent van Gogh's *Wheat Fields Under Cloudy Sky* originally featured bold
reds. But scientists at the University of Antwerp discoved that the red
lead paint used to create the vibrancy contains a mineral compound that
fades in the light.
Credit:

Courtesy of WikiCommons

Also known as red lead, plumbonacrite is suspected to be one of the first
synthetically-made paints known to man, and van Gogh was a particular fan
of the stuff. In many of his paintings he used bold colors — including the
red hue — which apparently degrades like a Gobstopper candy
<http://hyperallergic.com/187745/the-chemistry-of-why-van-gogh-reds-are-going-white/>
when
exposed to light.

Francesca Casadi, a conservation scientist with the Art Institute of Chicago
<http://www.artic.edu/>, says "We have known for some time that some of the
pigments that van Gogh used alter with time. But honestly I was quite
surprised to find that the red lead the mineral pigment that typically is
considered relatively stable also failed him."

Casadi says that at the time many artists like van Gogh were swept up my
the insdustrial revolution and it's impact on the art world — like the
manufacturing of paint.

"This is the time right after the industrial revolution when pigment was
manufactured. You don’t have the work-ship or assistance grinding minerals
and having all control on the production, you have the first industrial
production. And I suspect that the failing of this red lead may have to do
with something in the way it was produced."

"Some of the industrial manufacturing did include impurities we know now
cause some of these changes," Casadi says. "But artists, of course, love
the convenience of buying paint in a tube and not having to make their own
paint."

To figure out how red lead was changing colors, the Belgium researchers
took a tiny white piece of van Gogh's*Wheat stack under a cloudy sky.
*They examined
the white speck under a microscope and fired x-ray lasers through the
sample to determine what minerals it contained.

Turns out that speck of paint was originally red.

The team of scientists note that, “this is the first reported occurrence of
this compound in a painting dating from before the mid 20th century.” But
this isn't the same reason
<http://hyperallergic.com/110385/the-chemistry-of-the-canvas-returning-the-red-to-a-renoir/>
why
Renior's 1883's *Madame Léon Clapisson* is fading. The red color used for
that painting comes from an insect known as a cochineal, which, when
exposed to light separates it's organic and inorganic compounds. That turns
the red in the Renior's work into a mellow gray color.

Casadi says that while it's considered unethnical to touch up the paintings
to restore them to their original vibrant redish hue, digital technology
does allow for us to see how the artist first painted their works of art.
For example, she says that the Van Gogh Museum in Amsterdam
<http://www.vangoghmuseum.nl/> has an app that allows the user to get an up
close look at van Gogh's work- on the surface and underneath the paint.

Francesca Casadio, a conservation scientist with the Art Institute of
Chicago says that her team is, "feverishly working on an accurate
re-colorizatoin," of van Gogh's *The Bedroom* from 1889. She says it's
another one of van Gogh's paintings that have faded over time.

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