You don't use ice as a reference.  With ice water, the same principles apply 
that apply to boiling water.  This is why these are convenient calibration 
check points.

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> On Jul 21, 2014, at 3:51 PM, jim s <[email protected]> wrote:
> 
> 
>> On 7/21/2014 11:36 AM, Hal Murray wrote:
>> [email protected]  said:
>>> >Ice water and boiling water coupled with altitude will give you two points.
>> Has anybody used a good thermometer to measure air pressure?
>> 
>> How much does the measured temperature vary between just barely boiling and a
>> good roiling boil?  Or in various locations within a pot of boiling water?
> When you are dealing with water phase changes, you are dealing with both 
> temperature and heat.  When you get up to a point like boiling, you have a 
> mass of water which is at the local boiling point and the only thing stopping 
> the water from going to steam phase is the amount of heat in the water.  Once 
> a pot of water is at rolling boil all of the water in the pan should be at 
> and stay at the boiling point till it is all gone.
> 
> Once you remove the heat, the boiling will slow and stop, and the temperature 
> will begin to fall as the water loses the heat.
> 
> As long as you maintain a balance between having the sensor too close to the 
> point you are applying heat, and keeping it immersed in boiling water, you 
> should be able to assume the local boiling point.  That boiling point has to 
> be adjusted for pressure, which affects the temp the most.  Also assuming 
> only water, and no other contaminants as mentioned by another poster.
> 
> The same sort of action occurs when water freezes, along with some other 
> oddball issues with the crystalization.  You can arrive at the freezing 
> point, and you will dwell there for some time as the water loses its heat and 
> becomes solid.
> 
> The thing that is different between freezing and boiling is that as long as 
> you have water and are boiling the temperature will remain at boiling, and no 
> higher.
> 
> With freezing, if you are measuring water as you cool it and remove heat, it 
> will go thru freezing with a pause as it goes to ice, then it can continue to 
> cool as cold as you like.
> 
> so when you are measuring by using ice as a reference, you should have frozen 
> the sensor or drilled it into the center of a block of ice, and let it come 
> to equilibrium in the ice w/o any freezing apparatus being active.  It should 
> come to the freezing point till all of the ice melts.
> 
> Jim
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