Did you get the syntax right when you issued the command? See the manual page for the correct syntax. And should not the group be "george" instead of "users"?

The permissions won't get automatically changed. There's no such logic at work. I don't think this should (or will) change.

Also, the files have not been associated with Icedove. Whether this should be so is another thing. That's probably not a common thing to do. Can you find Icedove in the list under right click > open with other app?

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