Dear David,
Trisquel 7 is based on *buntu 14.04, this means it is a release with long-term support and perfect for working in a stable environment until 2019. However, this unfortunately means that you won't be able to install Plasma 5 because the preconditions of the 14.04 release are insufficient.
Only Trisquel 8 will enable you to install Plasma 5.

You can learn more about it at https://trisquel.info/en/wiki/how-trisquel-made

In GNU/Linux you will generally have to decide between stability and bleeding edge-software. In regard to this question, Trisquel plays on the serious side of the game. ;-)

Cheers,
Juergen

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