I do not think it makes any difference: in both cases, the CPU probably runs at the lowest available frequency ('cpufreq-info' in a terminal can tell you the current frequencies). The same holds for the GPU (if you have a separate video card). You can reduce the brightness of the screen to save energy. And do not believe that a black background wastes less energy than a white background: it was the case with CRT screens but it is not true for LCD screens (it usually is the opposite!): https://www.scientificamerican.com/article/fact-or-fiction-black-is/

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