I use GNOME Shell. I always open, full screen, the same applications on the same workspace:

Emacs;
Icedove;
Liferea;
Abrowser
GNOME Terminal;
Something else (usually Atril).

By defining keyboard shortcuts to switch to each of those workspaces, the navigation cannot be faster. Also, Alt+[key above Tab] allows to navigate between the windows of a same application (typically between Icedove's main window and another one where you write an email). The Activities Overview is great to launch applications: press [System (Windows)]", the first letter(s) of the application and [Enter]. I do not think there exists a more efficient way to launch applications (well, beside defining and remembering a keyboard shortcut or each of them).

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