In Xfce, synaptic-pkexec in a terminal gives:

Password:
polkit-agent-helper-1: error response to PolicyKit daemon: GDBus.Error:org.freedesktop.PolicyKit1.Error.Failed: No session for cookie
==== AUTHENTICATION FAILED ===
Error executing command as another user: Not authorized

The desktop icon does nothing, expectedly.

In Mate, synaptic-pkexec in a terminal triggers the password prompt which grants me admin privileges, same as clicking on the desktop icon.

NB: executing (Alt+F2) synaptic launches synaptic without privileges, in both environments.

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