In Xfce, synaptic-pkexec in a terminal gives:
Password:
polkit-agent-helper-1: error response to PolicyKit daemon:
GDBus.Error:org.freedesktop.PolicyKit1.Error.Failed: No session for cookie
==== AUTHENTICATION FAILED ===
Error executing command as another user: Not authorized
The desktop icon does nothing, expectedly.
In Mate, synaptic-pkexec in a terminal triggers the password prompt which
grants me admin privileges, same as clicking on the desktop icon.
NB: executing (Alt+F2) synaptic launches synaptic without privileges, in both
environments.