http://www.tvtechnology.com/dlrf/one.php?id=1080

NIST Seeks Cure for Metallic Whiskers

You may remember several years ago metallic "whiskers" were suspected of 
causing problems with multiple in-orbit satellites, including the loss 
of Galaxy 4. These whiskers are believed to form as a result of a 
metal's releasing stress generated by electroplating. Researchers at the 
National Institute of Standards and Technology (NIST) working with the 
International Electronics Manufacturing Initiative (INEMI) are trying to 
identify the origins of the whisker producing stresses. They reported 
that the surfaces of tin-copper deposits developed extremely long 
whiskers, while pure tin deposits produced only hillocks, a more benign 
growth.

The problem has become more acute as environmental groups have 
campaigned against lead-containing solders and protective layers on 
electronic components. The European Union will ban use of lead in all 
electrical and electronic equipment sold in EU nations next July.

Pure electroplated tin and lead-free tin alloys tend to spontaneously 
grow metallic whiskers, which can short out connections, causing 
equipment to fail. NIST researchers found that the whiskers and hillocks 
form when boundaries between individual grains have a column-shaped 
structure. Hillocks form when the boundaries move laterally. If the 
copper impurities hold the columnar boundaries immobile, whiskers form. 
Tin-lead deposits don't have this problem because the boundaries are 
randomly structured.

NIST researchers are investigating ways to eliminate the stresses and 
create structures without column grains. One way to accomplish this may 
be to use an interrupted alternating current electroplating process to 
disrupt the formation of columnar boundaries, instead of the traditional 
continuous current method. This could yield a structure similar to that 
of a tin-lead deposit, but without the environmental dangers of lead.

To view pictures of hillocks and whiskers, see the NIST Techbeat article 
NIST Seeking Cure for Electronics-Killing Whiskers. 
http://www.nist.gov/public_affairs/techbeat/tb2005_1117.htm#whiskers


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