Please try this solution posted at
(https://answers.edge.launchpad.net/ubuntu/+source/k3b/+question/92662).

Stop using any AUTO settings and don't use AUTO in any of the drop down
box options.  Choose DAO and ISO9660 to burn an image or iso. Now DAO
appears as the default option when I open K3b.  Choose SAO to burn a dvd
data disc.

Please get back if you have any queries.  Thanks in advance.

-- 
Empty Disc Recognised, but still Asks for Empty DVD upon Burn
https://bugs.launchpad.net/bugs/490205
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