I had the same exact issue but then I unmounted my usb key unplugged and
plugged it back in when the icon appeared on my desktop I right clicked
and selected format and it quickly formatted after it finished I went
back to the usb creator and it worked and finished making my startup
drive now I am off to try booting up some other pc's woohoo!

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Mounted USB harddrive showes twice on the desktop - right click one of the 
icons and choose "Unmount Volume" results in error "DBus error 
org.gtk.Private.RemoteVolumeMonitor.NotFound: The given mount was not found"
https://bugs.launchpad.net/bugs/251991
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