This can happen for a few different reasons I can think of.

1) permissions issue
2) something interfering in startup programs
3) upgrade from 9.10 may have broke it

For 1), make sure your regular user owns everything in ~/.gonf* then set 
appearance radio button to None then back again
For 2), check your startup programs
For 3), (which btw I think is the most probable even if you didn't upgrade:)

Login
Start compiz
Close all other open windows
Navigate to System>Preferences>Startup Applications> Options tab and click 
Remember Currently Running Application
Relogin; test

Hope this helps

-- 
Compiz settings gets reset with every restart
https://bugs.launchpad.net/bugs/588151
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