@Dave Jeffery - your issue could be a known bug in cairo 1.10 when exporting 
objects with opaque gradients to PDF:
Bug #681512 “Opaque radial gradients cause PDFs to fail to open in Adobe Reader”
Bug #672686 “Some diagrams results in "Illegal character" in the generated pdf”

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https://bugs.launchpad.net/bugs/664335

Title:
  pdf export with cairo 1.10 defaults to version PDF-1.5

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