man nv says:
Option "CrtcNumber" "integer"
Many graphics cards with NVIDIA chips have two video outputs.
The driver attempts to autodetect which one the monitor is con‐
nected to. In the case that autodetection picks the wrong one,
this option may be used to force usage of a particular output.
The options are "0" or "1". Default: autodetected.
so you could try setting:
Option "CrtNumber" "0"
--
xorg won't start on nvida 6600 card due to nv driver not supporting 6600's
https://bugs.launchpad.net/bugs/102683
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