This solution , found here, worked for me.
http://askubuntu.com/questions/8696/cannot-connect-to-google-talk-using-empathy-pidgin-after-upgrading

Try this:

   1. Add Google Talk account
   2. Login ID: [email protected]
   3. Password: **
   4. [x] Encryption required (TLS/SSL)
   5. [x] Ignore SSL certificate errors
   6. Resource:
   7. Priority: 0
   8. Server: talk.google.com
   9. Port: 443
  10. [x] Use old SSL

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https://bugs.launchpad.net/bugs/704197

Title:
  google chat and facebook won't connect

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