I confirm the same problem in my asus 8jc. I have 2 external USB disks 
connected, I receive this not-very-helpful message when I try to unmount. 
Even if I close all applications, same message appears. 
Trying from the terminal gives me:

[EMAIL PROTECTED]:~$ sudo umount /media/LaCie/
umount: /media/LaCie: device is busy

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Cannot unmount volume: not very helpful error message
https://bugs.launchpad.net/bugs/81239
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