I get the same behaviour, but I think I can add some extra details.
I have several network share directories bookmarked within Nautilus, but
because some apps can't see those bookmarks, I also have a directory
"Network" which is a symbolic link to ~/.gvfs
I find that using libreoffice, I can "save as" to a new file name on a
network share as long as I navigate through the file structure through
my "Network" symbolic link.
I get the error shown in the attached screen snapshot when I attempt to
go via a Nautilus bookmark.
I also checked another app ("gedit") to see if that failed also, but I
was able to do a "save as" through Nautilus bookmark fine.
** Attachment added: "Libreoffice Authentication required"
https://bugs.launchpad.net/ubuntu/+source/libreoffice/+bug/768915/+attachment/2130285/+files/Screenshot.png
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https://bugs.launchpad.net/bugs/768915
Title:
LibreOffice repeatedly asks for Samba file share credentials
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