I have the same error in 10.04 LTS. Libreoffice works when calling it as root, 
but not as user. I thought it was something related to folders permission, 
since I have copied out and back in my files and some of them were accessible 
only to the root user, but after changing that, re-installing Ubuntu, 
re-installing (the 3rd time) Libre ofice 3.3, the problem persists.
I also removed some language paks, what got me suspicious about, but -again- 
after purging and re-installing LO, it doesn't work!

Go figure  :-(

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https://bugs.launchpad.net/bugs/792947

Title:
  The application cannot be started.  A general error occurred while
  accessing your central configuration.

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