Thank you for reporting this bug.
I can reproduce it too.
I've changed Totem for VLC and double-click on a video file. Totem is opened
instead of VLC.
Output of "dpkg -l gnome-control-center":
ii gnome-control-center 1:3.4.2-0ubuntu0.5
Version of ubuntu: Ubuntu 12.04.1 LTS
** Package changed: ubuntu => gnome-control-center (Ubuntu)
** Changed in: gnome-control-center (Ubuntu)
Status: New => Confirmed
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https://bugs.launchpad.net/bugs/995906
Title:
"Default Applications" not being applied
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