I am also having this problem again since the upgrade to 12.10.

I get

Error saving the document <filename>:
Nonexistent file.

then

Error saving the document <filename>:
General Error.
General Input/output error.

then the LibreOffice window cannot be closed via the GUI.

Not sure if this is related, but It seems the "mount" point changed from 
$HOME/.gvfs/<share> to /run/user/$USER/gvfs/<share>.
Save As works for me if I change to a directory under 
/run/user/$USER/gvfs/<share>.

Ubuntu 12.10 x86_64
Version 3.6.2.2 (Build ID: 360m1(Build:2))

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https://bugs.launchpad.net/bugs/792622

Title:
  [Packaging] Libreoffice should use gnome vfs

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