I can confirm the method in comment #23 works for me at UNIVPM (Ancona -
Italy) with Ubuntu 13.04 Raring 64bit.

This is what I have done:
1) Connect to Eduroam using Networrk Manager inserting name, password and 
ignoring the certificate request. The connection fails, but the associated 
network profile appears in "/etc/NetworkManager/system-connections/eduroam"
2) Turn off WI-Fi
3) Open the terminal and edit the network profile with "sudo nano 
/etc/NetworkManager/system-connections/eduroam"
4) Change the line "system-ca-certs=true" to "system-ca-certs=false"
5) Turn on Wi-Fi
6) Connect to Eduroam using Network-Manager as usual

Looking ad the network profile I have seen that the line "system-ca-
certs=false" was removed, therefore I think that also the method in
comment #19 works, but it did not for me.

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https://bugs.launchpad.net/bugs/1104476

Title:
  Network manager cannot connect to WPA2/PEAP/MSCHAPv2 network without
  CA_Certificate

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