It sounds to me like ther is something broken with your installatino, as
I just installed a fresh instance of Ubuntu 13.10 on a machine, and all
GTK/GNOME apps are working just fine.

Unfrotunately I have no idea what may be broken, but under normal
circumstances, you most certainly don't need to define LD_LIBRARY_PATH.

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https://bugs.launchpad.net/bugs/1273826

Title:
  Gnome applications wont launch

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