Ok, searching"xfce ctrl space" or "ubuntu ctrl space" one case that others have 
found this to be an issue is with IBus. See the links for description and 
workaround.
http://askubuntu.com/q/243639
http://peter-butkovic.blogspot.com/2013/05/keyboard-shortcut-ctrlspace-caught-in.html

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https://bugs.launchpad.net/bugs/1344752

Title:
  key combo Shift-Ctrl-Space (non-breaking space) does not work

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