I think the problem is not related to NetworkManager but dhclient itself. 
Trying to use DHCPv6 in a Debian 8 machine (no GUI/NM) (using "iface eth0 inet6 
dhcp" in /etc/network/interfaces) the "dhclient -6" instance is not started 
either). Only after I run dhclient manually once (as observed by the OP) it 
starts working. I use:

# dhclient -6 -d eth0

Doing this the DUID (type 1) is generated and the configuration manager
works as expected (networkmanager in Ubuntu or ifup/ifdown in Debian).

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https://bugs.launchpad.net/bugs/1484932

Title:
  ipv6 dhcp client never started.

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