> The theme matching works only for ambiance?
It works only for the themes that are shipped within the snap.
As of today, for the libreoffice snap those are:
$ ls /snap/libreoffice/current/usr/share/themes/
Adwaita Ambiance Default Emacs Radiance Raleigh
That will eventually be fixed, but it will take some time.
For an explanation of why, see
When the theme used by your desktop is not found in the snap, I believe
it falls back to the first one in the list, which happens to be Adwaita.
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[snap] Libreoffice uses the adwaita gtk theme
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