Could it be that libreoffice is explicitly configured to invoke
/usr/bin/thunderbird, instead of delegating to xdg-email?

If you open the Tools menu > Options, Internet > E-mail, is the "E-mail
program" textbox empty? If not, what are its contents? Can you clear it,
save the configuration, and try again to send the current document by
e-mail?

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https://bugs.launchpad.net/bugs/1779804

Title:
  libreoffice cannot send document by email

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