I've tracked this down to the bug discussed in this thread:
https://askubuntu.com/questions/1529418/some-applications-start-very-
slow-after-boot-on-ubuntu-24-04

The fix for me was just do uninstall xdg-desktop-portal-gnome

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https://bugs.launchpad.net/bugs/2138190

Title:
  Theme resets to light mode on restart

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