This sounds a lot like a bug that's been reported upstream:
http://bugzilla.gnome.org/show_bug.cgi?id=512857. Can you attach the
output of 'banshee --debug'?
** Changed in: banshee (Ubuntu)
Status: New => Incomplete
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banshee crashes on usb flash drive mount (Gutsy)
https://bugs.launchpad.net/bugs/151003
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