By using nasos method, I identified ghostscript to be the process which is 
blocking my memory stick.
in the root directory of the stick were indeed some .ps files which could not 
be opened by ghostscript.
Tests with moving the files brought me to a theory:
After plugging in the memory stick, the file browser opens and the file 
previews are created by helper programs. In my case this is ghostscript.
If the helper program has problems opening a file it may get blocked. So the 
file in question is still accessed and the media can not be unmounted.

As a workaround, i deactivated the image previews in the file browser
under Edit - Preferences - Previews - Other files with possibility to
preview. This solved my problems unmounting the device.

Actually, I don't think the problem has a relation with the gnome-
volume-manager, because it does exactly what it has to do: reject
unmounting a device which is in use.  It seems more to be a problem,
where the file browser works with the helper applications.

-- 
Cannot unmount volume: not very helpful error message
https://bugs.launchpad.net/bugs/81239
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