It looks like you've installed php5 from gutsy-updates
(5.2.3-1ubuntu6.3), then removed gutsy-updates from your sources.list,
so you're getting php5-pgsql from gutsy-security (5.2.3-1ubuntu6.2).
Re-add updates to your sources.list again, and all should be well with
the world.
** Changed in: php5 (Ubuntu)
Status: New => Invalid
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[gutsy] php5-pgsql packages are BROKEN
https://bugs.launchpad.net/bugs/210143
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