dear Ashutosh Kumar,
the LO-TO splitting comes from macroscopic electric fields that build up 
in the cell of polar materials.
however you are using occupations='smearing' which is appropriate for 
metals where no electric field can be calculated.
remove the occupation='smearing' bit so that the code knows you are 
woking with an insulator.

stefano

Ashutosh Kumar wrote:
> Sorry, I forgot to write the error I was getting. With InP, it says
>               task #         0
>               from phq_readin : error #         1
>               no elec. field with metals
>
> with q=0. I tried the example02 for Si and C, and it worked fine, but in InP, 
> it keeps on saying above. 
>
> Extremely sorry for writing again the symmetry problem in Ge. I searched the 
> forum about germanium and read many of those results, but could not find 
> anything, so I wrote the problem here.
>
>
> Ashutosh Kumar
> Grad Student
> The Ohio State University
>
> ________________________________________
> From: pw_forum-bounces at pwscf.org [pw_forum-bounces at pwscf.org] on behalf 
> of pw_forum-request at pwscf.org [pw_forum-request at pwscf.org]
> Sent: Wednesday, March 31, 2010 2:28 PM
> To: pw_forum at pwscf.org
> Subject: Pw_forum Digest, Vol 33, Issue 83
>
> Send Pw_forum mailing list submissions to
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> Today's Topics:
>
>    1. Symmetry problem in Ge and phonon calculation problem in  InP
>       (Ashutosh Kumar)
>    2. Re: (no subject) (Gabriele Sclauzero)
>    3. about xcrysden (Shaptrishi Sharma)
>    4. Re: phonon dispersion for graphene (Elie Moujaes)
>    5. Re: phonon dispersion for graphene (Paolo Giannozzi)
>    6. Re: Symmetry problem in Ge and phonon calculation problem in
>       InP (Paolo Giannozzi)
>    7. Re: problems with Ta2O5 compound (Paolo Giannozzi)
>    8. Re: hi (Paolo Giannozzi)
>
>
> ----------------------------------------------------------------------
>
> Message: 1
> Date: Wed, 31 Mar 2010 15:49:02 +0000
> From: Ashutosh Kumar <kumar.198 at buckeyemail.osu.edu>
> Subject: [Pw_forum] Symmetry problem in Ge and phonon calculation
>         problem in      InP
> To: "pw_forum at pwscf.org" <pw_forum at pwscf.org>
> Message-ID:
>         <6D7E0C0F56302745BD0EC910BF4FF30813FB0201 at 
> BL2PRD0103MB037.prod.exchangelabs.com>
>
> Content-Type: text/plain; charset="iso-8859-1"
>
> Dear pwscf users
>
> I've been trying to do phonon calculations, for elemental and compound 
> semiconductors(Si, Ge, InP and SiC). Si and Ge both have exactly the same 
> structure and space group, so symmetry operations are also same. Below is the 
> self consistent input file, i'm using. In case of Si and Ge, the scf.out file 
> works with all the 48 symmetry operations but in case of Ge it rejects all 
> the inversion symmetry opertors. Also, for further calculations i'm using 
> exactly the procedure given in example07 directory.
>
> Also, for InP, I used the same procedure, but i'm missing the splitting of 
> phonon spectra at higher frequency, as reported in publications. After going 
> through the forums, I got to know that I should use zasr=.true. and 
> epsil=.true. for calculations in InP, since it is a polar semiconductor. I 
> tried this and the phonon calculation job keeps on crashing. I don't 
> understand what should I do to solve this problem?
>
>
>  &control
>     calculation='scf'
>     restart_mode='from_scratch',
>     prefix='ge',
>     pseudo_dir = '/nfs/18/osu5465/espresso/espresso-3.2/pseudo/',
>     outdir='/nfs/18/osu5465/espresso/tmp/'
>  /
>  &system
>     ibrav= 2, celldm(1) =10.691, nat=2 , ntyp= 1,
>     ecutwfc =25.0,
>     occupations='smearing', smearing='methfessel-paxton', degauss=0.05,
>  /
>  &electrons
>     conv_thr =  1.0d-8
>     mixing_beta = 0.7
>  /
> ATOMIC_SPECIES
>  Ge  72.61   Ge.pz-bhs.UPF
> ATOMIC_POSITIONS {crystal}
> Ge     0.250000  0.250000    0.25000000
> Ge     0.000000  0.000000    0.00000000
> K_POINTS {automatic}
>  8 8 8 0 0 0
>
> --
> Ashutosh Kumar
> Grad Student
> The Ohio State University
> -------------- next part --------------
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> ------------------------------
>
> Message: 2
> Date: Wed, 31 Mar 2010 17:59:08 +0200
> From: Gabriele Sclauzero <sclauzer at sissa.it>
> Subject: Re: [Pw_forum] (no subject)
> To: PWSCF Forum <pw_forum at pwscf.org>
> Message-ID: <4BB3714C.9080109 at sissa.it>
> Content-Type: text/plain; charset=ISO-8859-1; format=flowed
>
> sylvia mueni wrote:
>   
>> hi im working on the latice constants of BaF2. I have a problem in 
>> determining the
>> atomic positions of the hexagonal phase. please help
>>     
>
> Which kind of problem?
>
> GS
>
> P.S. please specify your affiliation. Thanks!
>
>   
>> thanks, sylvia
>>
>>
>>
>>
>>
>> ------------------------------------------------------------------------
>>
>> _______________________________________________ Pw_forum mailing list
>> Pw_forum at pwscf.org http://www.democritos.it/mailman/listinfo/pw_forum
>>     
>
> --
>
>
> o ------------------------------------------------ o
> | Gabriele Sclauzero, PhD Student                  |
> | c/o:   SISSA & CNR-INFM Democritos,              |
> |        via Beirut 2-4, 34014 Trieste (Italy)     |
> | email: sclauzer at sissa.it                         |
> | phone: +39 040 3787 511                          |
> | skype: gurlonotturno                             |
> o ------------------------------------------------ o
>
>
> ------------------------------
>
> Message: 3
> Date: Wed, 31 Mar 2010 17:12:56 +0100
> From: Shaptrishi Sharma <sh.shapt at gmail.com>
> Subject: [Pw_forum] about xcrysden
> To: pw_forum at pwscf.org
> Message-ID:
>         <j2ta8a0c4081003310912ja99b91b5vd10b645460b11338 at mail.gmail.com>
> Content-Type: text/plain; charset="iso-8859-1"
>
> Hi there,
>
> I am not much familar with xcrysden. I wanted to make a supercell in
> xcrysden with a certain cell_parametrs (in put file of scf calculation in
> quantum espresso), but on going to option 'Modify' and then try to draw the
> number of units to 3 along y and z axis. It shows me that certain number of
> atoms are being deleted. I have checked the cell_parameter by changing the
> cell_parameter , but not much help. Kindly help !
> Thanks
>
> Shaptarishi
>
> Msc (Physics)
> Pune
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> ------------------------------
>
> Message: 4
> Date: Wed, 31 Mar 2010 18:40:10 +0100
> From: Elie Moujaes <elie.moujaes at hotmail.co.uk>
> Subject: Re: [Pw_forum] phonon dispersion for graphene
> To: <pw_forum at pwscf.org>
> Message-ID: <SNT114-W5535D5628F735BE0382F62D31E0 at phx.gbl>
> Content-Type: text/plain; charset="iso-8859-1"
>
>
> Thanks very much for your reply. What if I want to plot the graph of 
> frequency versus the wavevector K specifying the Gamma, K and M points..Can 
> one do this in one go or does he have to calculate the frequencies for each 
> of the points separately and then connect them.
>
>
>
> N.B: I was trying to use ldisp=true and provide an nq1 x nq2 x nq3 grid and I 
> got the previous error. Any examples dealing with this?
>
>
>
>
>
> Thanks
>
>
>
> Elie Mouaes
>
> University of Nottingham
>
> NG7 2RD
>
> UK
>
>   
>> Date: Wed, 31 Mar 2010 17:16:57 +0200
>> From: nnlinh at sissa.it
>> To: pw_forum at pwscf.org
>> Subject: Re: [Pw_forum] phonon dispersion for graphene
>>
>> Your input file lacks the points where you want to calculate phonon
>> dispersion (Gamma, X, ...)
>> So, you should see in example02 for reference of phonon input file
>>
>> Good luck
>> Linh
>>
>> Elie Moujaes wrote:
>>     
>>> Sear PWSCF users,
>>>
>>> I am calculating the phonon dispersion for graphene. I did the scf
>>> calculations then when I am running the ph.x command, I always get the
>>> error:
>>>
>>>
>>>
>>> Program PHONON v.4.1.2 starts ...
>>> Today is 31Mar2010 at 12: 1:50
>>>
>>> Ultrasoft (Vanderbilt) Pseudopotentials
>>>
>>> %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
>>> from phq_readin : error # 1
>>> reading inputph namelist
>>> %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
>>>
>>> stopping ...
>>>
>>>
>>>
>>>
>>> which means that something is wrong in the input. But I could not fins
>>> any mistake in the input file...Can anyone please check it for me? My
>>> input is:
>>>
>>>
>>>
>>>
>>>
>>>
>>>
>>> &inputph
>>>
>>> tr2_ph=1.0d-14,
>>>
>>> prefix='ph mono graphene',
>>>
>>> ldisp=.true.,
>>>
>>> nq1=28, nq2=28, nq3=1,
>>>
>>> amass(1)=12.00000,
>>>
>>> outdir='/tmp/results_MOUJAES/',
>>>
>>> fildyn='phmgraphene.dyn'
>>>
>>> /
>>>
>>>
>>>
>>> Thanks
>>>
>>>
>>>
>>> Elie Moujaes
>>>
>>> University of Nottingham
>>>
>>> NG7 2RD
>>>
>>> UK
>>>
>>>
>>>
>>>
>>>
>>>
>>> ------------------------------------------------------------------------
>>> Got a cool Hotmail story? Tell us now
>>> <http://clk.atdmt.com/UKM/go/195013117/direct/01/>
>>> ------------------------------------------------------------------------
>>>
>>> _______________________________________________
>>> Pw_forum mailing list
>>> Pw_forum at pwscf.org
>>> http://www.democritos.it/mailman/listinfo/pw_forum
>>>
>>>       
>> --
>> -----------------------------------------------------
>> Nguyen Ngoc Linh, PhD Student
>> c/o: SISSA & CNR-INFM Democritos,
>> via Beirut 2-4, 34014 Trieste (Italy)
>> email: nnlinh at sissa.it
>> phone: +39 04 03787 319
>> skype: ngoclinh84phys
>> -----------------------------------------------------
>> "The physics is theoretical but the fun is real"
>>
>>
>> _______________________________________________
>> Pw_forum mailing list
>> Pw_forum at pwscf.org
>> http://www.democritos.it/mailman/listinfo/pw_forum
>>     
>
> _________________________________________________________________
> Tell us your greatest, weirdest and funniest Hotmail stories
> http://clk.atdmt.com/UKM/go/195013117/direct/01/
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> ------------------------------
>
> Message: 5
> Date: Wed, 31 Mar 2010 19:52:37 +0200
> From: Paolo Giannozzi <giannozz at democritos.it>
> Subject: Re: [Pw_forum] phonon dispersion for graphene
> To: PWSCF Forum <pw_forum at pwscf.org>
> Message-ID: <A8AC1F4B-8966-45DE-BC4E-8991A5DCF8E9 at democritos.it>
> Content-Type: text/plain; charset=US-ASCII; delsp=yes; format=flowed
>
>
> On Mar 31, 2010, at 19:40 , Elie Moujaes wrote:
>
>   
>>  N.B: I was trying to use ldisp=true and provide an nq1 x nq2 x nq3
>> grid and I got the previous error. Any examples dealing with this?
>>     
>
> examples/example06
>
> ---
> Paolo Giannozzi, Dept of Physics, University of Udine
> via delle Scienze 208, 33100 Udine, Italy
> Phone +39-0432-558216, fax +39-0432-558222
>
>
>
>
>
> ------------------------------
>
> Message: 6
> Date: Wed, 31 Mar 2010 20:04:05 +0200
> From: Paolo Giannozzi <giannozz at democritos.it>
> Subject: Re: [Pw_forum] Symmetry problem in Ge and phonon calculation
>         problem in InP
> To: PWSCF Forum <pw_forum at pwscf.org>
> Message-ID: <EC8CE1AB-745D-499C-B4FE-F2EDF5F72DF2 at democritos.it>
> Content-Type: text/plain; charset=US-ASCII; delsp=yes; format=flowed
>
>
> On Mar 31, 2010, at 17:49 , Ashutosh Kumar wrote:
>
>   
>> In case of Si and Ge, the scf.out file works with all the 48
>> symmetry operations
>> but in case of Ge it rejects all the inversion symmetry opertors.
>>     
>
> congratulations! this is the 1000000th time somebody reports this.
> You win the
> right to write parallel symmetrization in G-space for the phonon
> code. Once you
> have done this, Ge will no longer reject any symmetry operation.
>
> By the way, is Ge in the first row different from Ge in the second?
>
>   
>> I tried this and the phonon calculation job keeps on crashing
>>     
>
> crashing how? If it crashes for a good reason, the reason is printed
> on output.
> If it crashes for no apparent reason: consider that many compilers
> miscompile
> the phonon code.
>
> P.
> ---
> Paolo Giannozzi, Dept of Physics, University of Udine
> via delle Scienze 208, 33100 Udine, Italy
> Phone +39-0432-558216, fax +39-0432-558222
>
>
>
>
>
> ------------------------------
>
> Message: 7
> Date: Wed, 31 Mar 2010 20:21:41 +0200
> From: Paolo Giannozzi <giannozz at democritos.it>
> Subject: Re: [Pw_forum] problems with Ta2O5 compound
> To: PWSCF Forum <pw_forum at pwscf.org>
> Message-ID: <F56577F0-9448-47C8-885C-C68662D0F7D9 at democritos.it>
> Content-Type: text/plain; charset=US-ASCII; delsp=yes; format=flowed
>
> On Mar 31, 2010, at 10:37 , Maxim Ivanov wrote:
>   
>> First of all energy gap is too small
>>
>>     
> this is a well known problem of DFT
>   
>> Moreover I have not find defect level in 14, 42, 168 atoms
>> supercells with oxygen vacancy in the center of the cell.
>>
>>     
> oxides are notoriously nasty stuff, in which sometimes you don't get
> things right
>   
>> Ta has 3 d electrons and is described by ultrasoft pseudopotential.
>> I took it from pwscf.org. It might be problem in the potential.
>>
>>     
> why should the problem be in the pseudopotential? any evidence, or
> any other
> calculations to compare with?
>
> P.
> ---
> Paolo Giannozzi, Dept of Physics, University of Udine
> via delle Scienze 208, 33100 Udine, Italy
> Phone +39-0432-558216, fax +39-0432-558222
>
>
>
>
>
> ------------------------------
>
> Message: 8
> Date: Wed, 31 Mar 2010 20:28:15 +0200
> From: Paolo Giannozzi <giannozz at democritos.it>
> Subject: Re: [Pw_forum] hi
> To: PWSCF Forum <pw_forum at pwscf.org>
> Message-ID: <4F276755-9D2E-4B92-B564-40DCABDA6616 at democritos.it>
> Content-Type: text/plain; charset=US-ASCII; format=flowed
>
>
> On Mar 31, 2010, at 10:15 , Thaneshwor Kaloni wrote:
>
>   
>> I am unable to get the seedname.eig file
>>     
>
> I guess you may get more help from the Wannier mailing list:
> http://www.wannier.org/forum.html
>
> P.
> ---
> Paolo Giannozzi, Dept of Physics, University of Udine
> via delle Scienze 208, 33100 Udine, Italy
> Phone +39-0432-558216, fax +39-0432-558222
>
>
>
>
>
> ------------------------------
>
> _______________________________________________
> Pw_forum mailing list
> Pw_forum at pwscf.org
> http://www.democritos.it/mailman/listinfo/pw_forum
>
>
> End of Pw_forum Digest, Vol 33, Issue 83
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