If an electron has negative Sz, its magnetic moment would be negative. Sz of
majority spin electrons in your system is negative.
Just flip the molecule (system) 180o (change direction of z coordinate) you
will get positive magnetic moments (but you don't have to).
--------------------------------------------------
Duy Le
PhD Student
Department of Physics
University of Central Florida.

"Men don't need hand to do things"


On Sun, Aug 22, 2010 at 2:02 PM, Padmaja Patnaik <
padmaja_patnaik at yahoo.co.uk> wrote:

> Dear all
> I have a doubt in the value obtained for local magnetic moment of the
> atoms. The pdos.out file, towards its end shows the value of polarization on
> each atom of the sample which gives us the value of local magnetic moment of
> each atom. Many of these values are found to be negative in my calculations.
> What does it mean? How can a magnetic moment value be negative?
>
>
> Regards
> Padmaja Patnaik
> Research Scholar
> Dept of Physics
> IIT Bombay
> Mumbai, India
>
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>
>
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