Dear All,
Please help reconcile this. I run PDOS calculations with 4d (Pd) dimers 
arranged on the surface
of graphene.
a. The L?wdin  charges for perpendicular dimer on Hexagonal site:
top atom
total charge=10.0581, d=9.3310
lower atom
total charge=9.7631,  d=9.2231 
b. The L?wdin charges for parallel dimer on Hexagonal site:
top atom
total charge=0.0613, d=0.0568
lower atom
total charge=0.0623, d=0.0571
The valence is 4d95s1? in the pseudopotential (pbe.rrkjus). My question here is 
that,
why is it that the representation lowdin charges is different in the two 
configurations? or does
the parallel configuration directly represent the charge transfer.
Thank you in anticipation of your kind response.

Yusuf Zuntu
Postgraduate student
University Putra Malaysia
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