Dear Qianqian,

Your atomic coordinate could be one of the reasons you are not getting the 
diagonal matrix! So you better send your input file completely, however 
sometimes if there is not a segmentation fault, changing diagonalization to 
?cg? might solve the problem.

Best,

Hadi.

From: pw_forum-bounces at pwscf.org [mailto:[email protected]] On 
Behalf Of Qianqian Wang
Sent: 06 May 2014 01:21
To: pw_forum at pwscf.org
Subject: [Pw_forum] Davidson diagonalization with overlap

Hi,
All users, I calculated a Ca-Si-O system. After vcrelax, I put one hydrogen 
into it and want to find a proper position for hydrogen in this system. But 
mostly, the jobs stopped at "Davidson diagonalization with overlap". I couldn't 
find the problem. Sometimes, it can run properly, but mostly, I couldn't get 
the proper results.
Maybe, the initial hydrogen positions are not good enough, but how can I get 
the proper results?
This is the input file:
&CONTROL
                 calculation = 'relax' ,
                      outdir = '/home/xxx' ,
                  pseudo_dir = '/home/xxx' ,
                      prefix = 'r1' ,
               etot_conv_thr = 1.0D-4 ,
               forc_conv_thr = 1.0D-3 ,
                       nstep = 500 ,
                     tstress = .true. ,
                     tprnfor = .true. ,
 /
 &SYSTEM
                       ibrav = 0,
                         nat = 29,
                        ntyp = 4,
                  tot_charge = +1 ,
                     ecutwfc = 45.D0 ,
                     ecutrho = 450.D0 ,
                 occupations = 'smearing' ,
                     degauss = 0.02 ,
                    smearing = 'methfessel-paxton' ,
                       nspin = 1 ,
                    noncolin = .false. ,
            exxdiv_treatment = 'gygi-baldereschi' ,
 /
 &ELECTRONS
            electron_maxstep = 500,
           scf_must_converge = .true. ,
                    conv_thr = 1.D-6 ,
                 mixing_beta = 0.3 ,
 /
 &IONS
                ion_dynamics = 'bfgs' ,
 /
 &CELL
               cell_dynamics = 'bfgs' ,
                       press = 0 ,

/
CELL_PARAMETERS angstrom
     5.101656231    0.000000000    0.000000000
     0.000000000   11.2966859      0.000000000
     0.000000000    0.000000000    6.787044
ATOMIC_SPECIES

Thank you very much!
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