Dear Yao-Hong
It seems that you are working in a very accurate way. I would only say that 
(maybe) d metals such as Cu hosted in sp semiconductors could benefit of a 
DFT+U treatment, but it is only my biased suggestion! Is it is the scf of the 
Cu-doped system that does not converge, or is it the BFGS?
Best Wishes
Giuseppe

On Tuesday, May 03, 2016 12:12:23 PM n16031320 wrote:
> Dear Giuseppe:
> 
> Thanks for your response, I use Ver.5.3.0 of QE and GGA in the form of PBE.
> 
> About the type of pseudopotential, I use PAW from THEOS, according to the 
> website it said that PAW type is widely tested and no error is reported.
> 
> I study some paper which is experiment, they dope with Ag and the percentage 
> up to 7%, so I think 6.25% may be ok.
> 
> I studied the paper which is about experiment, it is said that SnSe doped 
> with Al, Pb and Cu for 2%,respectively, don't change lattice parameter too
> much,
> 
> so I decided to do the relax calculation instead of vc-relax first for doped 
> with Pb and Al for 6.25%, and the result show that the position of
> atoms don't change too mush,
> 
> then I check the total force is <0.0004&#160;, I think the result of 
> relaxation is reasonable.&#160;
> 
> First I use 12 processors for the vc-relax calculation, now I use 48 
> processors for the relax calculation,&#160;
> 
> the relax calculation for the doped with Al and Pb for 6.25% is done, but 
> doped with Cu for 6.25% is still running, maybe 6.25% is too large for
> Cu?&#160;
> 
> Also I will try to dope with lower percent too.
> 
> And what things I should pay attention to, any advice? Thanks!
> 
> Regards
> 
> Yao-Hong Huang
> 
> --
> 
> Graduate student
> 
> Department of Mechanical Engineering
> 
> National Cheng Kung University
> 
> Tainan, Taiwan

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   Giuseppe Mattioli                            
   CNR - ISTITUTO DI STRUTTURA DELLA MATERIA   
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