Dear Stefano,

No, point symmetry doesn’t depend on units, i.e. squeezing or expanding the 
system equally in all directions doesn’t change symmetry. I agree!

The presence of the inversion symmetry is not to save computational time, but 
to correct for possible dipole interactions.

Anyway, the point is that neb.x is not able to detect and to use the symmetry 
of the involved images. This is weird, since the task of optimising/calculating 
the images
will be delegated to pw.x, I suppose. And I showed that pw.x detects and uses 
the symmetry. Maybe the keyword ``use_all_frac     = .true.`` is not considered 
for a NEB calculation.



Met vriendelijke groeten,
Mit freundlichen Grüßen,
With kind regards,


Willem Offermans
Researcher Electrocatalysis SCT
VITO NV | Boeretang 200 | 2400 Mol
Phone:+32(0)14335263 Mobile:+32(0)492182073

[email protected]<mailto:[email protected]>

[cid:[email protected]]

On 13 Feb 2019, at 10:04, Stefano Baroni 
<[email protected]<mailto:[email protected]>> wrote:



On 13 Feb 2019, at 09:50, Offermans Willem 
<[email protected]<mailto:[email protected]>> wrote:

Dear Quantum Espresso friends,

Dear Wilem:

I made a mistake in my previous e-mail.
The atom coordinates are not in Angstrom but in Bohr.

I have corrected this in my calculations, but still no symmetry found.

I would be surprised if you found the contrary. I cannot imagine that the point 
symmetry of any system could depend on units: do you?

$ grep "ymmetr" pd_?/PW.out
pd_1/PW.out:     No symmetry found
pd_2/PW.out:     No symmetry found
pd_3/PW.out:     No symmetry found
pd_4/PW.out:     No symmetry found
pd_5/PW.out:     No symmetry found
pd_6/PW.out:     No symmetry found
pd_7/PW.out:     No symmetry found

So the question remains. What is the reason that the symmetry cannot be 
detected?

As an extra check I have made a scf calculation on the last image.

$ grep "Sym. Ops." pd.out
      2 Sym. Ops., with inversion, found ( 1 have fractional translation)

So pw.x can find the symmetry whereas neb.x cannot!

Just guessing: maybe for some reasons neb restricts its search to pure 
rotations (no fractional translations involved). Also, I have the impression 
that inversion symmetry does not help save any computer time, because in 
practice it has the same effects as time-reversal symmetry, which always holds.

Just my worthless 5 cents …
SB


—
Stefano Baroni - Trieste —  http://stefano.baroni.me<http://stefano.baroni.me/>




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