Have you checked this? 
http://www.sogo.nu/english/nc/support/faq/article/cant-send-mail-via-the-the-web-interface-2.html

postconf -e strict_rfc821_envelopes=no




Burkart Orlowski

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On 09.09.2011, at 20:16, <[email protected]> <[email protected]> wrote:

Hi,
I'v installed Dovecot, Postfix and SOGo under Ubuntu Server 10.04. The access
to the IMAP-account via the webinterface works. But when I try to send an email
via the webinterface I get the message

Warning
Cannot send message: all recipients are invalid.

The log says

C: connect to <0x0x98ab618[NGInternetSocketAddress]: host=192.168.1.1
not-filled>
S: <SMTP-Reply: code=220 line='testserver ESMTP Postfix (Ubuntu)'>
C: EHLO testserver.local
S: <SMTP-Reply: code=250 line='DSN'>
S: pipelining extension supported.
S: size extension supported.
C: MAIL FROM:<testuser@testserver>
C: RCPT TO:<[email protected]>
Sep 09 19:10:03 sogod [1743]: <0x0x95bc3e8[SOGoMailer]> error with recipient
'[email protected]'
C: QUIT
S: <SMTP-Reply: code=221 line='2.0.0 Bye'>
2011-09-09 19:10:03.971 sogod[1743] ERROR: could not open MySQL4 connection to
database 'sogo': Can't connect to MySQL server on '192.168.1.1' (111)
Sep 09 19:10:03 sogod [1743]: [ERROR] <0x0x952e8f0[GCSChannelManager]> could
not open channel <MySQL4Channel[0x0x97e1050] connection=0x(null)> for URL:
mysql://sogo:[email protected]:3306/sogo/sogo_user_profile
Sep 09 19:10:03 sogod [1743]: [WARN] <0x0x952e8f0[GCSChannelManager]>   will
prevent opening of this channel 5 seconds after 2011-09-09 19:10:03 +0200
Sep 09 19:10:03 sogod [1743]: [ERROR] <0x0x97ca048[SOGoSQLUserProfile]> failed
to acquire channel for URL:
mysql://sogo:[email protected]:3306/sogo/sogo_user_profile
127.0.0.1 - - [09/Sep/2011:19:10:03 GMT] "POST
/SOGo/so/testuser/Mail/0/folderDrafts/newDraft1315588172-1/send HTTP/1.1" 200
84/2244 17.084 - - 256K

Any ideas, I struggle with it for hours without success?

Rgds
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