We're able to send mail from Thunderbird no problem, SSL are the only open 
ports (993 and 465), Outlook can't seem to send mail though. I'm guessing that 
I need to edit a setting in the outgoing server preferences in Outlook, but I 
thought I did all that right (use ssl with pw authentication). Relevant lines 
in mail.log:

Oct 24 16:04:48 sogo dovecot: imap-login: Login: user=<marym>, method=PLAIN, 
rip=94.61.55.105, lip=192.168.0.16, mpid=16100, TLS
Oct 24 16:04:48 sogo dovecot: imap-login: Login: user=<marym>, method=PLAIN, 
rip=94.61.55.105, lip=192.168.0.16, mpid=16103, TLS
Oct 24 16:04:48 sogo dovecot: imap(marym): Disconnected: Disconnected in IDLE 
bytes=46/450
Oct 24 16:04:48 sogo dovecot: imap(marym): Disconnected: Logged out 
bytes=203/3166
Oct 24 16:06:51 sogo dovecot: imap-login: Login: user=<marym>, method=PLAIN, 
rip=94.61.55.105, lip=192.168.0.16, mpid=16129, TLS
Oct 24 16:06:51 sogo postfix/smtps/smtpd[16088]: NOQUEUE: reject: RCPT from 
mail5.mydomain.com[94.61.55.105]: 554 5.7.1 <mail5.mydomain.com[94.61.55.105]>: 
Client host rejected: Access denied; from=<[email protected]> 
to=<[email protected]> proto=ESMTP helo=<MaryPC>
Oct 24 16:08:03 sogo postfix/smtps/smtpd[16088]: NOQUEUE: reject: RCPT from 
mail5.mydomain.com[94.61.55.105]: 554 5.7.1 <mail5.mydomain.com[94.61.55.105]>: 
Client host rejected: Access denied; from=<[email protected]> 
to=<[email protected]> proto=ESMTP helo=<MaryPC>
Oct 24 16:12:01 sogo postfix/smtps/smtpd[16088]: NOQUEUE: reject: RCPT from 
mail5.mydomain.com[94.61.55.105]: 554 5.7.1 <mail5.mydomain.com[94.61.55.105]>: 
Client host rejected: Access denied; from=<[email protected]> 
to=<[email protected]> proto=ESMTP helo=<MaryPC>-- 
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