<mime-mapping>
    <extension>dotx</extension>
   
<mime-type>application/vnd.openxmlformats-officedocument.wordprocessingml.template</mime-type>
  </mime-mapping>

It's enough.

But in any case - in your example you have error. compare with my variant.
You can see, that in a line:
"<extension>dotx</extension>" you haven't last ">" ...

Also, I attached FULL list of MIME-types for all MSOffice and OpenOffice
Applications. Standart XWiki installation have only some of them ...
http://xwiki.475771.n2.nabble.com/file/n6029499/x2scrap2.txt x2scrap2.txt 
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